6-Nitro-1-β-napthalenesulfonyloxybenzotriazole : A novel coupling reagent for peptide synthesis
✍ Scribed by Balekudru Devadas; Bijoy Kundu; Alka Srivastava; Krishna B Mathur
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- French
- Weight
- 145 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
We report the synthesis of 3,4-dihydro-3-methyl-6-nitro-2 \(H\)-1,3-benzoxazin-2-one (DMNB), a close structural analogue of \(p\)-nitrophenyl dimethylcarbamate. DMNB is unstable in aqueous solution when exposed to light, but is stable in the dark. The compound reacts slowly with chymotrypsin as an a
Glycals can be readily hydrated using the LaCl 3 •7H 2 O/NaI/PhCH 2 OH reagent system. In one case, having an exo methylene group, such hydration gives an intermediate which is readily converted into 1,6-dideoxynojirimycin, a potential enzyme inhibitor.