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ChemInform Abstract: 1-Butyl-3-methylimidazolium p-Toluenesulfinate: A Novel Reagent for Synthesis of Sulfones and β-Ketosulfones in Ionic Liquid.

✍ Scribed by Anil Kumar; Manoj Kumar Muthyala

Publisher
John Wiley and Sons
Year
2012
Weight
34 KB
Volume
43
Category
Article
ISSN
0931-7597

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Rhodium Acetate Dimer Immobilized in 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid: a Novel and Recyclable Catalytic System for the Cyclopropanation of Alkenes
✍ J. S. Yadav; B. V. S. Reddy; P. Narayana Reddy 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 92 KB 👁 2 views

Alkenes undergo smooth cyclopropanation with ethyl diazoacetate using a catalytic amount of rhodium acetate dimer, Rh 2 (OAc) 4 , immobilized in the air-and moisture-stable 1-butyl-3-methylimidazolium hexafluorophosphate ionic liquid, [bmim]PF 6 , to afford cyclopropanecarboxylates in excellent yiel