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6-Chloro-2-(4-chlorophenoxy)-2-thioxo-4-trichloromethyl-4H-1,3,2-benzodioxaphosphorine

✍ Scribed by Krishnaiah, M. ;Radha Krishna, J. ;Jagadeesh Kumar, N. ;Devandranath Reddy, C. ;Rao, S. N.

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 121 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s160053680700092x

No coin nor oath required. For personal study only.

✦ Synopsis

In the title compound, C 14 H 8 Cl 5 O 3 PS, the six-membered dioxaphosphorine ring exhibits a boat conformation with the S atom in an equatorial and the trichloromethyl group in an axial position. The benzene rings are oriented at dihedral angles of 17.77 (15) and 19.47 (19) with respect to the mean plane of the heterocyclic ring.

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6-Chloro-2-(4-chloro­phen­oxy)-2-thioxo-4-trichloro­methyl-4H-1,3,2-benzodioxaphospho­rine

✦ Synopsis

6-Chloro-2-(4-chlorophenoxy)-2-thioxo-4-trichloromethyl-4H-1,3,2-benzodioxaphosphorine