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5,5′-Dithiobis(1-phenyl-1H-tetrazole)

✍ Scribed by Brito, Iván ;Cárdenas, Alejandro ;Mundaca, Aldo ;Villalobos, Hada ;López-Rodríguez, Matías


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
293 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The structure of the title compound, C 14 H 10 N 8 S 2 , comprises two 1-phenyl-1H-tetrazole-5-thiolate units linked by an S-S disulfide bridge. The C-S-S-C torsion angle is 81.9 (1) . C-HÁ Á ÁN hydrogen bonding, with CÁ Á ÁN = 3.413 (4) A ˚and C-HÁ Á ÁN = 147 , link the molecules into supramolecular chains in the crystal structure.


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## Abstract A new and convenient synthesis of a variety of __N__‐ and __S__‐substituted tetrazoles has been developed via azide and Mannich reaction methods. Compounds were characterized by elemental analysis, MALDI MS, and ^1^H NMR data. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:637–643, 2