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51V NMR studies of a system vanadium pentoxide-potassium pyrosulfate

โœ Scribed by Mastikhin, V. M. ;Lapina, O. B. ;Lyakhova, V. F.


Book ID
112688591
Publisher
Springer
Year
1980
Tongue
English
Weight
200 KB
Volume
14
Category
Article
ISSN
0133-1736

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Vanadium pentoxide gels are formed via the reaction of V 2 O 5 powder with hydrogen peroxide. 51 V NMR studies of the solution show that the dissolution of the oxide leads to the formation of solute diperoxo [VO(O 2 ) 2 ] ุŠ species. These peroxo species are not stable in the solution. They progressi