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Vanadium-51 NMR as a probe of vanadium(V) coorination to human apotransferrin

✍ Scribed by Butler, Alison; Eckert, Hellmut


Book ID
126919780
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
920 KB
Volume
111
Category
Article
ISSN
0002-7863

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Vanadium pentoxide gels are formed via the reaction of V 2 O 5 powder with hydrogen peroxide. 51 V NMR studies of the solution show that the dissolution of the oxide leads to the formation of solute diperoxo [VO(O 2 ) 2 ] ؊ species. These peroxo species are not stable in the solution. They progressi