Xanes and 51V Nmr study of vanadium-oxygen compounds
β Scribed by M. Nabavi; F. Taulelle; C. Sanchez; M. Verdaguer
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 792 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0022-3697
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π SIMILAR VOLUMES
Vanadium pentoxide gels are formed via the reaction of V 2 O 5 powder with hydrogen peroxide. 51 V NMR studies of the solution show that the dissolution of the oxide leads to the formation of solute diperoxo [VO(O 2 ) 2 ] Ψ species. These peroxo species are not stable in the solution. They progressi
## Abstract ^51^V quadrupolar central transition NMR spectra of buffered (pH 7.6β8.0) solutions of bovine apoβtransferrin (Tf) and bovine prostatic acid phosphatase (Pp) treated with vanadate show normal features (chemical shifts between β515 and β542 ppm) corresponding to the complexation of VO~2~