51V and 13C NMR spectroscopic study of the peroxovanadium intermediates in vanadium catalyzed enantioselective oxidation of sulfides

Studies directed toward the prediction o

Studies directed toward the prediction of the oxidative reactivity of vanadium peroxo complexes in water. Correlations between the nature of the ligands and 51V-NMR chemical shifts

✍ Valeria Conte; Fulvio Di Furia; Stefano Moro 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 968 KB

The "V-NMR spectroscopic behavior in water of a series of vanadium peroxo complexes was investigated. Monoperoxo vanadium complexes containing bidentate ligands in which the two binding sites are either oxygen atoms (0 f~ 0 ligands) or one oxygen and one nitrogen atom (N n 0 ligands) and diperoxo va