5-Nitrosalicylaldehyde benzoylhydrazone
✍ Scribed by Ali, Hapipah M. ;Puvaneswary, Subramaniam ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 150 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
Nearly planar molecules of the title compound, C 11 H 11 N 3 O 4 , are linked by O-HÁ Á ÁO hydrogen bonds to form zigzag chains along the c axis; adjacent chains are, in turn, linked by weaker N-HÁ Á ÁO hydrogen bonds to form layers perpendicular to the a axis of the orthorhombic unit cell.
📜 SIMILAR VOLUMES
Molecules of 5-chlorosalicylaldehyde benzoylhydrazone, C 14 H 11 ClN 2 O 2 , are linked by an intermolecular aminocarbonyl hydrogen bond into a linear chain that runs along the a axis of the orthorhombic unit cell.
The molecule of the title compound, C~14~H~11~N~3~O~5~, is approximately planar, the dihedral angles between the two aromatic rings being 4.63 (7)°. O—H...N, N—H...O and O—H...O hydrogen bonds and π–π stacking interactions help to consolidate the crystal packing.
An i.r. study of Fe complexes prepared from salicylaldehyde benzoyl hydrazone and seven similar chelating agents allowed the assignment of some iron-ligand bands. The amide I and ~b--O band shifts indicate that the ligand O atoms are directly linked to Fe. The analogy between FdI and Fe In complexes
In the title structure, C 16 H 12 N 4 O 3 Á0.5H 2 O, the uncoordinated water molecule lies on a special position of site symmetry 2; O-HÁ Á ÁO and N-HÁ Á ÁO hydrogen bonds link the water and organic molecules into a layer structure.