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5-Chloro­salicylaldehyde benzoyl­hydrazone

✍ Scribed by Ali, Hapipah M. ;Puvaneswary, Subramaniam ;Ng, Seik Weng


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
215 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


Molecules of 5-chlorosalicylaldehyde benzoylhydrazone, C 14 H 11 ClN 2 O 2 , are linked by an intermolecular aminocarbonyl hydrogen bond into a linear chain that runs along the a axis of the orthorhombic unit cell.


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The molecule of the title compound, C~14~H~11~N~3~O~5~, is approximately planar, the dihedral angles between the two aromatic rings being 4.63 (7)°. O—H...N, N—H...O and O—H...O hydrogen bonds and π–π stacking interactions help to consolidate the crystal packing.

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An i.r. study of Fe complexes prepared from salicylaldehyde benzoyl hydrazone and seven similar chelating agents allowed the assignment of some iron-ligand bands. The amide I and ~b--O band shifts indicate that the ligand O atoms are directly linked to Fe. The analogy between FdI and Fe In complexes

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The molecules of the title compound, C 16 H 16 N 2 O 4 , are linked by hydrogen bonds into a zigzag chain running along the c axis of the monoclinic cell.