5-Nitropyrimidines from 3,3-diamino(2-nitro)thioacrylamides. Structure of 6-(2-furfurylamino)-2-(2-furyl)-4-methylthio-5-nitropyrimidine
✍ Scribed by Linden, A. ;Heimgartner, H. ;García Trimiño, M. I. ;Macías Cabrera, A.
- Book ID
- 114510594
- Publisher
- International Union of Crystallography
- Year
- 1994
- Tongue
- English
- Weight
- 400 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0108-2701
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Dichloro-2-(methylthio)-5-nitropyrimidine has been utilized as a building block for an efficient nine-step synthesis of olomoucine. The methodology reported herein is applicable to the regiocontrolled solution and solid-phase synthesis of libraries of highly substituted purines, as well as other rel
The s y n t h e s i s of t h e 5 -n i t r o f u r a n 2,4-diacetylamino-6-(5-nitro-2-furyl)- is d e s c r i b e d . F u r y l l i t h i u m i n e t h e r i s c a r b o x y l a t e d w i t h radio-carbon d i o x i d e g e n e r a t e d from Ba14COj. The furoic-carbonyl-14C a c i d is t h e n e s t e