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(5-Carboxy-1H-pyrazole-3-carboxylato-κ2N2,O3)bis(1,10-phenanthroline-κ2N,N′)cobalt(III) perchlorate 2.5-hydrate

✍ Scribed by Xie, Hui-Dong ;Xie, Cheng-Zhi ;Wang, Xiao-Qing ;Shen, Guang-Qiu ;Shen, De-Zhong

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
139 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

1H-pyrazole-3-carboxylatoj 2 N 2 ,O 3 )bis(1,10-phenanthroline-j 2 N,N 0 0 0 )cobalt(III) perchlorate 2.5-hydrate

📜 SIMILAR VOLUMES

Bis[3-chloro-6-(3,5-dimethyl-1H-pyrazol-
Bis[3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl-κN2)picolinato-κ2N,O]cobalt(II) 2.5-hydrate
✍ Zhao, Kai ;Yin, Xian-Hong ;Feng, Yu ;Zhu, Jie 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 806 KB

In the title compound, [Co(C 11 H 9 ClN 3 O 2 ) 2 ]Á2.5H 2 O, the Co II atom, which lies on a twofold rotation axis, is coordinated by four N atoms and two O atoms from two ligands in a distorted octahedral geometry. In the crystal structure, molecules are linked together by intermolecular O-HÁ Á ÁO

catena-Poly[[(1,10-phenanthroline-κ2N,N′
catena-Poly[[(1,10-phenanthroline-κ2N,N′)(pyridine-3-carboxylato-κ2O:O′)cadmium(II)]-μ-pyridine-3-carboxylato-κ3N:O,O′]
✍ Yi, Hong-Chao ;Mei, Ping 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 553 KB

The title complex, [Cd(C 6 H 4 NO 2 ) 2 (C 12 H 8 N 2 )] n , is a onedimensional chain-like coordination polymer. Adjacent chains are further aggregated into a three-dimensional network through -(interplanar distance is 3.5806 A ˚) and C-HÁ Á Á interactions.