A new Schiff base-copper(II) complex:
[5-Bromo-N-(2-pyridylethylsulfanylethyl)salicylideneiminato-κ4N,N′,O,S]copper(II) perchlorate
✍ Scribed by Saghatforoush, Lotf A. ;Hossaini Sadr, Moayad ;Lewis, William ;Wikaira, Jan ;Robinson, Ward T. ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 183 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 113 K Mean '(C±C) = 0.006 A Ê R factor = 0.039 wR factor = 0.107 Data-to-parameter ratio = 15.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
l-Oxalato-1j 2 O,O 0 0 0 :2j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis(chloro{[1-(2pyridyl-jN)ethylidene]hydrazine-jN}copper(II)
In the title compound, [Cu(C 16 H 16 N 4 ) 2 ](ClO 4 ) 2 , the Cu II atom lies on an inversion centre and has a distorted square-planar geometry. In each ligand, the dihedral angle between the triazole and pyridine rings is 9.1 (3) , and that between the triazole and benzene rings is 85.01 ( 14) .
The crystal structure of the title compound, [Ni(C 15 H 10 Cl 2- N 2 O 2 )(C 5 H 5 N) 3 ]ÁC 5 H 5 N, is built of molecules of a mononuclear nickel complex and uncoordinated solvent pyridine molecules. The Ni II atom in the complex is coordinated by two O and one N atoms of the meridional tridentate