The title compound, [Ni(C 13 H 7 Br 2 N 2 O) 2 ], an Ni II complex of the Schiff base 2-(3,5-dibromo-2-hydroxyphenyl)benzimidazole, was synthesized by the reaction of 3,5-dibromosalicylaldehyde and 1,2-phenylenediamine. The molecule resides on a twofold rotation axis. The Ni II atom exists in a dist
[(4RS,7SR)-1-(1H-Benzimidazol-2-ylmethyl-κN3)-1,4,7-triazacyclononane-κ3N]bromidocopper(II) bromide
✍ Scribed by Li, Qing-Xiang ;He, Bing-Zhong ;Shen, Jun-Yun ;Xiao, Hai-Yan
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 166 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.038 wR factor = 0.106 Data-to-parameter ratio = 13.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [Cu(N 3 ) 2 (C 27 H 33 N 3 )], the copper(II) atom is coordinated by five N atoms from the 1,4,7-tribenzyl-1,4,7-triazacyclononane ligand and the azide ions in a slightly distorted square-pyramidal geometry.
Tetrakis(2,2 0 0 0 -bipyridine)-1j 4 N,N 0 0 0 ;-4j 4 N,N 0 0 0 -hexa-l-iodido-1:2j 4 I:I;-2:3j 4 I:I;3:4j 4 I:I-1,4-dicadmium(II)-2,3-disilver(I)