(4RS,5R)- und (4RS,5S)-4-Methoxy-5-methyloxazolidin-2-on-Derivate aus Threonin - interessante chirale Amidoalkylierungsreagentien
✍ Scribed by Christiane Herborn; Andrea Zietlow; Prof. Dr. Eberhard Steckhan
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 319 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Die Synthesen der Titelverbindungen (**15** und **25**) aus D‐Glucose werden beschrieben. Schlüssel‐verbindungen sind die Tetradesoxytrimethylendithioacetale **11** und **23**, die nach der Corey‐Seebach‐Methode mit THP‐geschütztem 3‐Brom‐1‐propanol zu den vollständig blockierten, offen
The title compound BDI is prepared on multigram scale, so clean that highly efficient in-situ double alkylations are feasible, in which the sequence of addition of the two either by resolution of the precursor 2-tert-butylimidazolidin-4-one (from glycine amide and pivalaldehyde) through different el
H 5 ÐC 2 N 2 OÐS, mÐNO 2 ÐC 6 H 4 ÐCH=CHÐCOO] Ð has been synthesized via the organic transformation reactions of the terephthaloyl chloride precursors Z-(C 5 H 5 )Fe(CO) 2 ECO(C 6 H 4 )COCl with the desired nucleophiles. These new complexes were characterized by elemental analysis, IR and 1 H NMR sp