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4,6-Diphenyl-1-(phenyl­sulfon­yl)-1H-furo[3,4-b]pyrrole

✍ Scribed by Moskalev, Nikolai V. ;Gribble, Gordon W. ;Jasinski, Jerry P.


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
230 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title molecule, C~24~H~17~NO~3~S, is the first example of the 1__H__-furo[3,4-b]pyrrole ring system to be described. It crystallizes with three molecules in the asymmetric unit. In each molecule, the fused heterocycle is planar and one of the two phenyl groups on the furan ring is only slightly out of planarity with the furan ring, while the other phenyl group is significantly twisted by 47.6 (4), 48.3 (3) and 54.1 (3)°.


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In the title compound, C 23 H 19 Br 2 NO 4 S, the orientation of the phenylsulfonyl substituent with respect to the indole ring system is influenced by intramolecular C-HÁ Á ÁO interactions. The sulfonyl-bound phenyl ring is orthogonal to the indole ring system. In the crystal structure,stacking int