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4,4′,4′′-(1,3,5-Triazine-2,4,6-tri­yl)tripyridinium trinitrate

✍ Scribed by Zhu, Shou-Rong ;Chen, Wan-Dong ;Zhao, Hong-Jian ;Shao, Min ;Li, Ming-Xing

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
284 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

Reaction of 2,4,6-tris(4-pyridyl)-1,3,5-triazine (tpt) with excess nitric acid in an aqueous solution affords the title compound, C~18~H~15~N~6~
^3+^·3NO~3~
^−^. The torsion angles between adjacent aromatic rings are much larger than those of neutral tpt. All three pyridine N atoms are protonated.

📜 SIMILAR VOLUMES

2,4,6-Tris(4-pyridylmethyl­sulfan­yl)-1,
2,4,6-Tris(4-pyridylmethyl­sulfan­yl)-1,3,5-triazine monohydrate
✍ Amoore, Jarrod J. M. ;Kepert, Cameron J. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 144 KB

In the crystal structure of the title compound, C 21 H 18 N 6 S 3 ÁH 2 O, the ligands are held together throughstacking interactions and O-HÁ Á ÁN hydrogen bonds involving the water molecule.

2,4,6-Tris(pyridin-2-ylsulfan­yl)-1,3,5-
2,4,6-Tris(pyridin-2-ylsulfan­yl)-1,3,5-triazine
✍ Galicia-López, Oscar ;Morales-Morales, David ;Hernández-Ortega, Simón 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 191 KB
2,4,6-Tris(2,4,6-tribromo­phen­oxy)-1,3,
2,4,6-Tris(2,4,6-tribromo­phen­oxy)-1,3,5-triazine
✍ Li, Feng ;Jiang, Hong-Quan ;Li, Xue-Mei ;Zhang, Shu-Sheng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 176 KB

In the title compound, C 21 H 6 Br 9 N 3 O 3 , the triazine ring is almost perpendicular to the three benzene rings. In the crystal structure, molecules are linked into a three-dimensional framework by C-HÁ Á ÁO interactions.

4,6-Dimorpholino-N-(2,4,4-trimethylpenta
4,6-Dimorpholino-N-(2,4,4-trimethylpentan-2-yl)-1,3,5-triazin-2-amine
✍ Dong, Jun-Ying ;Huang, Peng-Mian 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 700 KB

In the title compound, C 19 H 34 N 6 O 2 , both morpholine rings adopt chair conformations. In the crystal structure, N-HÁ Á ÁN hydrogen bonds link the molecules into chains along c.