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2,4,6-Tris(4-pyridylmethyl­sulfan­yl)-1,3,5-triazine monohydrate

✍ Scribed by Amoore, Jarrod J. M. ;Kepert, Cameron J.

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
144 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the crystal structure of the title compound, C 21 H 18 N 6 S 3 ÁH 2 O, the ligands are held together throughstacking interactions and O-HÁ Á ÁN hydrogen bonds involving the water molecule.

📜 SIMILAR VOLUMES

5-Phenyl-3-[3-(5-phenyl-1,2,4-triazin-3-
5-Phenyl-3-[3-(5-phenyl-1,2,4-triazin-3-ylsulfan­yl)­propyl­sulfan­yl]-1,2,4-triazine
✍ Wen, Li-Rong ;Zhou, Jian-Xia ;Liu, Peng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 107 KB

The title compound, C 21 H 18 N 6 S 2 , crystallizes with one halfmolecule in the asymmetric unit; a twofold rotation axis passes through the central C atom. The triazine ring makes a dihedral angle of 10.65 (2) with the benzene ring.

4,4′,4′′-(1,3,5-Triazine-2,4,6-tri­yl)tr
4,4′,4′′-(1,3,5-Triazine-2,4,6-tri­yl)tripyridinium trinitrate
✍ Zhu, Shou-Rong ;Chen, Wan-Dong ;Zhao, Hong-Jian ;Shao, Min ;Li, Ming-Xing 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 284 KB

Reaction of 2,4,6-tris(4-pyridyl)-1,3,5-triazine (tpt) with excess nitric acid in an aqueous solution affords the title compound, C~18~H~15~N~6~ ^3+^·3NO~3~ ^−^. The torsion angles between adjacent aromatic rings are much larger than those of neutral tpt. All three pyridine N atoms are protonated.

2,4,6-Tris(pyridin-2-ylsulfan­yl)-1,3,5-
2,4,6-Tris(pyridin-2-ylsulfan­yl)-1,3,5-triazine
✍ Galicia-López, Oscar ;Morales-Morales, David ;Hernández-Ortega, Simón 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 191 KB