In the title compound, C 18 H 18 N 2 O 2 S, the torsion angle about the N-S bond between the quinoline ring system and the benzene ring is À60.9 (2) . The NH group forms an intramolecular hydrogen bond to the quinoline N atom.
4-Nitro-N-(8-quinolyl)benzenesulfonamide
✍ Scribed by da Silva, Luiz Everson ;Joussef, Antonio Carlos ;Foro, Sabine ;Schmidt, Boris
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 268 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 15 H 11 N 3 O 4 S, the dihedral angle between the quinoline ring system and the benzene ring is 79.9 (3) . Intermolecular hydrogen bonds of types N-HÁ Á ÁO, C-HÁ Á ÁO and C-HÁ Á ÁN are observed.
📜 SIMILAR VOLUMES
In the title compound, C 15 H 11 BrN 2 O 2 S, the torsion angle about the central C-N-S-C bridge is 55. 1 (5) . The dihedral angle between the planes of the nearly planar quinoline group and the bromobenzene ring is 72.0 (1) . No classical hydrogen bonds were found in the crystal structure.
Single-crystal X-ray study T = 299 K Mean (C-C) = 0.004 A R factor = 0.046 wR factor = 0.131 Data-to-parameter ratio = 12.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the molecule of the title compound, m-(O 2 N)C 6 H 4 NHSO 2 -C 6 H 4 -p-Me or C 13 H 12 N 2 O 4 S, the planes of two benzene rings are orthogonal to each other [dihedral angle 92.4 (1) ].