In the crystal structure of the title compound, C 26 H 34 N 2 O 3 S, the quinoline ring system, with methoxy and methyl substituents, is nearly planar. An intramolecular hydrogen bond [N-HÁ Á ÁN = 2.16 (2) A ˚] is observed.
2,4,6-Triisopropyl-N-(8-quinolyl)benzenesulfonamide
✍ Scribed by da Silva, Luiz Everson ;Joussef, Antonio Carlos ;Foro, Sabine ;Schmidt, Boris
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 510 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, C 15 H 11 N 3 O 4 S, the dihedral angle between the quinoline ring system and the benzene ring is 79.9 (3) . Intermolecular hydrogen bonds of types N-HÁ Á ÁO, C-HÁ Á ÁO and C-HÁ Á ÁN are observed.
In the title compound, C 18 H 18 N 2 O 2 S, the torsion angle about the N-S bond between the quinoline ring system and the benzene ring is À60.9 (2) . The NH group forms an intramolecular hydrogen bond to the quinoline N atom.
Single-crystal X-ray study T = 299 K Mean (C-C) = 0.004 A R factor = 0.046 wR factor = 0.131 Data-to-parameter ratio = 12.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [Zn(C 24 H 29 N 2 O 2 S) 2 ], the Zn atom is four-coordinated by the N atoms of the sulfonamide and quinoline groups. The crystal packing is stabilized by intermolecular C-HÁ Á ÁO hydrogen bonds.