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4′-Hydrazone Derivatives of 2,2′:6′,2"-Terpyridine: Protonation and Substituent Effects

✍ Scribed by Jonathon E. Beves; Edwin C. Constable; Catherine E. Housecroft; Markus Neuburger; Silvia Schaffner; Jennifer A. Zampese

Book ID
102828438
Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
750 KB
Volume
2008
Category
Article
ISSN
1434-193X

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✍ Jonathon E. Beves; Edwin C. Constable; Catherine E. Housecroft; Markus Neuburger 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 German ⚖ 378 KB 👁 1 views

## Abstract The syntheses of the five 2,2′: 6′,2″‐terpyridine (tpy) ligands 5–9 functionalized in the 4′‐position with a hydrazone substituent RR′CNNH (R=R′=Me; R=H, R′=4‐BrC~6~H~4~, 4‐O~2~NC~6~H~4~, 4‐MeOC~6~H~4~, or 3,5‐(MeO)~2~C~6~H~3~) are described. Protonation of the tpy domain of the ligan