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Polyaza cavity shaped molecules. 4. Annelated derivatives of 2,2':6',2"-terpyridine

✍ Scribed by Thummel, Randolph P.; Jahng, Yurngdong

Book ID: 118134380
Publisher: American Chemical Society
Year: 1985
Tongue: English
Weight: 804 KB
Volume: 50
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00214a001

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## Abstract The syntheses of the five 2,2′: 6′,2″‐terpyridine (tpy) ligands 5–9 functionalized in the 4′‐position with a hydrazone substituent RR′CNNH (R=R′=Me; R=H, R′=4‐BrC~6~H~4~, 4‐O~2~NC~6~H~4~, 4‐MeOC~6~H~4~, or 3,5‐(MeO)~2~C~6~H~3~) are described. Protonation of the tpy domain of the ligan