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4-Amino-5-(2-ethoxyphenyl)-2,4-dihydro-2H-1,2,4-triazole-3-thione–triphenylphosphine oxide (1/1)

✍ Scribed by Chen, Xi-An ;Huang, Xiao-Bo ;Wu, Hua-Yue

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 717 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807024774

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✦ Synopsis

In the title compound, C 18 H 15 OPÁC 10 H 12 N 4 OS, the triazole ring makes a dihedral angle of 51.24 (7) with the attached benzene ring. The triazole ring and its thione substituent are delocalized. There are intermolecular N-HÁ Á ÁO and N-HÁ Á ÁS hydrogen bonds, which also involve the cocrystallized triphenylphosphine oxide molecule.

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View of (I) showing 50% probability displacement ellipsoids and the atom-numbering scheme.