The title compound, C 22 H 14 N 2 O 3 , contains three benzene rings, pairs of which form dihedral angles of 55.37 (5), 68.47 (4) and 82.82 (4) . The average C-O-C angle is 119.0 (1) .
4-(4-Allyl-2-methoxyphenoxy)benzene-1,2-dicarbonitrile
✍ Scribed by Şahin, Onur ;Büyükgüngör, Orhan ;Şaşmaz, Selami ;Kantar, Cihan
- Book ID
- 104491757
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 758 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C~18~H~14~N~2~O~2~, the dihedral angle between the two benzene rings is 88.6 (1)°. The allyl group is disordered over two orientations, with refined occupancies of 0.695 (6) and 0.305 (6). The methoxy group is coplanar with the attached benzene ring. C—H...N intermolecular hydrogen bonds link the molecules into a C(6) chain along the a axis. The chain structure is further strengthened by C—H...π interactions.
📜 SIMILAR VOLUMES
In the title compound, C 16 H 12 N 2 O 2 , the 2-methoxyphenoxy and phthalonitrile planes make a dihedral angle of 83.42 (7) .
The title compound, C 11 H 15 NO 3 , was synthesized from 4methoxyphenol and 2-methyl-4,5-dihydrooxazole under nitrogen. There are two independent molecules in the asymmetric unit, which are connected into one-dimensional chains via intermolecular N-HÁ Á ÁO hydrogen bonds. ## Related literature O