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2-tert-Butylthio-4-methylbicyclo[2.1.1]hexane-1,2-dicarbonitrile

✍ Scribed by Tinant, B. ;Declercq, J. P.

Book ID
114507126
Publisher
International Union of Crystallography
Year
1990
Tongue
English
Weight
216 KB
Volume
46
Category
Article
ISSN
0108-2701

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4-(4-Allyl-2-methoxyphenoxy)benzene-1,2-
4-(4-Allyl-2-methoxyphenoxy)benzene-1,2-dicarbonitrile
✍ Şahin, Onur ;BΓΌyΓΌkgΓΌngΓΆr, Orhan ;Şaşmaz, Selami ;Kantar, Cihan πŸ“‚ Article πŸ“… 2007 πŸ› International Union of Crystallography 🌐 English βš– 758 KB

In the title compound, C~18~H~14~N~2~O~2~, the dihedral angle between the two benzene rings is 88.6β€…(1)Β°. The allyl group is disordered over two orientations, with refined occupancies of 0.695β€…(6) and 0.305β€…(6). The methoxy group is coplanar with the attached benzene ring. Cβ€”H...N intermolecular hyd

Thermal unimolecular isomerization of 1,
Thermal unimolecular isomerization of 1,4-dimethylbicyclo[2.2.0]hexane, 1,4-dimethylbicyclo[2.1.1]hexane, and 1,4-dimethylbicyclo[2.1.0]pentane
✍ R. Srinivasan πŸ“‚ Article πŸ“… 1969 πŸ› John Wiley and Sons 🌐 English βš– 593 KB

The thermal isomerization of the title compounds was studied in the vapor phase. Over the temperature range from 445.1 to 477.5"K7 1,4-dimethylbicyclo[2.2.O]hexane underwent a homogeneous unimolecular reaction to 2,5-dimethyl-175-hexadiene, the rate constants being represented by the equation: k =