304 Å pes of the ti 5d levels in ti and tii
✍ Scribed by Şefik Süzer
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 278 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Tl5d photoel2c:ron spectra of TI and TlI ar2 compared It IS observed that the multdme character of atomrc 5dsn subshell romzatron drsappears m the molecular case This disappearance is attnbuted to the transfer of the 6ptn electron to rodme when the molecule 15 formed. The transfer of the 6p t,s electron mhrbrts a two-electron (one-electrondown-oneelectron-up) contiguratron mteractlon mechamsm operatrre for the atom whrch IS responsible ior the mult&ne character of :hc ntomtc spectrum_
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## Abstract The capacity of the imido‐nitrido organometallic ligand [{Ti(η^5^‐C~5~Me~5~)(μ‐NH)}~3~(μ~3~‐N)] (1) to entrap main group metal halides MX~__n__~ has been investigated. Treatment of 1 with metal halides in toluene or dichloromethane afforded several soluble adducts [MX~__n__~(L)] (L=1) i