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3-Methyl-α-himachalene: Proposed structure for novel homosesquiterpene sex pheromone ofLutzomyia longipalpis(diptera: Psychodidae) from Jacobina, Brazil

✍ Scribed by J. G. C. Hamilton; G. W. Dawson; J. A. Pickett

Book ID
105440661
Publisher
Springer
Year
1996
Tongue
English
Weight
553 KB
Volume
22
Category
Article
ISSN
0098-0331

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Enantioselective synthesis of (1S,3S,7R)
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1S,3S,7R)-3-Methyl-a-himachalene, the sex pheromone of the male sand¯y (Lutzomyia longipalpis) from Jacobina, Brazil, was synthesized enantioselectively by employing Evans' or Oppolzer's asymmetric methylation as the key step. The absolute con®guration at the ring junction of this pheromone is oppos

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Four stereoisomers (1a-d) of (±)-3-methyl-α-himachalene produced sex pheromone of the sandfly Lutzomyia longipalpis was shown to possess the structure and relative were synthesized by employing the intramolecular Diels-Alder reaction of (±)-14 to (±)-18 as the key-step. The male-configuration as dep

ChemInform Abstract: 3-Methyl-α-himachal
ChemInform Abstract: 3-Methyl-α-himachalene is Confirmed, and the Relative Stereochemistry Defined, by Synthesis as the Sex Pheromone of the Sandfly Lutzomyia longipalpis from Jacobina, Brazil.
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