3-Methyl-1,4-diphenyl-1H,5H,7H-furo[3,4-b]pyrazolo[4,3-e]pyridin-5-one
✍ Scribed by Chen, Dong-Qin ;Tu, Shu-Jiang
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 117 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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Single-crystal X-ray study T = 120 K Mean '(C±C) = 0.002 A Ê R factor = 0.040 wR factor = 0.110 Data-to-parameter ratio = 15.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C 19 H 16 BrN 3 O, was synthesized by the reaction of 5-amino-3-methyl-1-phenylpyrazole with 4-bromophenylaldehyde and Medrum's acid in glycol under microwave irradiation. X-ray crystal structure analysis reveals three crystallographically independent molecules in the asymmetric
## Abstract Die Darstellung einer Reihe von neuen 1H‐Pyrazolo[3,4‐b]‐pyridin‐5‐ketonen wird beschrieben. In einer modifizierten __Gould‐Jacobs__‐Reaktion dienen dabei die 5‐Aminopyrazole **4** und Aethoxymethylen‐β‐keto‐ester **3** als Ausgangsverbindungen. Sind die Ketoester **1** schlecht zugängl