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{3-[(E)-(5-Bromo-2-oxidophen­yl)methyl­amino]­propanoato-κ3O,N,O′}(1,10-phenanthroline-κ2N,N′)­copper(II) dihydrate

✍ Scribed by Liu, Zheng ;Zhang, Shu-Hua ;Feng, Xiao-Zhen ;Li, Guang-Zhao ;Lin, Yuan-Bin

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
298 KB
Volume
63
Category
Article
ISSN
1600-5368

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Bis(glycolato-κ2O,O′)(1,10-phenanthrolin
Bis(glycolato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)copper(II) dihydrate
✍ Du, Lin ;Zhang, Yu-Hua ;Fang, Rui-Bing ;Zhao, Qi-Hua 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 236 KB

The title mononuclear complex, [Cu(C 2 H 3 O 3 ) 2 (C 12 H 8 N 2 )]Á-2H 2 O, is isostructural with its zinc(II) analogue. The Cu atom in the complex exists in a distorted octahedral coordination environment, defined by four O atoms and two N atoms. O-HÁ Á ÁO hydrogen bonds andstacking interactions h

{[(5-Bromo-2-oxidophenyl)methyleneamino]
{[(5-Bromo-2-oxidophenyl)methyleneamino]methanesulfonato-κ3O,N,O′}(methanol-κO)(1,10-phenanthroline-κ2N,N′)cadmium(II)
✍ Xu, Jin-Sheng ;Zhang, Chun-Hua ;Kuang, Dai-Zhi ;Feng, Yong-Lan ;Peng, Yun-Lin 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 822 KB

The title compound, [Cd(C 8 H 6 BrNO 4 S)(C 12 H 8 N 2 )(CH 4 O)], incorporating a Schiff base formed by aminomethanesulfonic acid and 5-bromosalicylaldehyde, was synthesized in a watermethanol solution. In the structure, the Cd II atom is sixcoordinated by one O atom from a methanol molecule, two N