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3-Deoxy-D-arabino-heptulosonic acid 7-phosphate: chemical synthesis and isolation from Escherichia coli auxotrophs

โœ Scribed by Frost, John W.; Knowles, Jeremy R.

Book ID
126149118
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
641 KB
Volume
23
Category
Article
ISSN
0006-2960

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โœ Mella Adlersberg; David B. Sprinson ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 418 KB

3-Deoxy-D-urubino-2-heptulosonic acid 7-phosphate (S), the first committed intermediate in aromatic amino acid biosynthesis, has been synthesized in good yield by treatment of methyl (methyl 3-deoxy-D-urubino-2-heptulopyranosid)onate with diphenylphosphoric chloride under mild conditions to give the