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A combined chemical-enzymic synthesis of 3-deoxy-D-arabino-heptulosonic acid 7-phosphate

โœ Scribed by Turner, Nicholas J.; Whitesides, George M.

Book ID
126265401
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
568 KB
Volume
111
Category
Article
ISSN
0002-7863

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Synthesis of 3-deoxy-d-arabino-2-heptulosonic acid 7-phosphate by phosphorylation of methyl (methyl 3-deoxy-d-arabino-heptulopyranosid)onate
โœ Mella Adlersberg; David B. Sprinson ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 418 KB

3-Deoxy-D-urubino-2-heptulosonic acid 7-phosphate (S), the first committed intermediate in aromatic amino acid biosynthesis, has been synthesized in good yield by treatment of methyl (methyl 3-deoxy-D-urubino-2-heptulopyranosid)onate with diphenylphosphoric chloride under mild conditions to give the