3-butenyl esters as convenient protecting groups for carboxylic acids
β Scribed by Anthony G.M. Barrett; Suzanne A. Lebold; Xiao-an Zhang
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- French
- Weight
- 201 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Carboxylic acids were protected as their corresponding 3-butenyl esters. Deprotection was carried out via ozonolysis and P-elimination of the resultant 3acyloxypropanal.
π SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
4-Quinolylmethyl (4-QUI) esters of carboxylic acids and 1-naphthyimethyi (1-NAP) esters of carbonic and carbamic acids are reduced by palladium-catalyzed hydrogenolysis by formate anion. The reaction conditions are compatible with the presence of a benzyl ester and of an alkene double bond.
Tetrahydro-1-naphthyl Ester as a Selective Protecting Group for Carboxylic Acids. -Various esters derived from tetrahydronaphthol are prepared by standard procedures. The ester group is selectively cleaved under mild conditions in the presence of other esters. In addition, the tetrahydronaphthyl es