𝔖 Bobbio Scriptorium
✦   LIBER   ✦

3-(1-Methyl-1-phenyl­ethoxy)-1,3-thia­zole-2(3H)-thione: a tertiary thio­hydroxamic acid O-ester

✍ Scribed by Hartung, Jens ;Schneiders, Nina ;Bergsträsser, Uwe

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
156 KB
Volume
62
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The steric demand of a tertiary alkyl substituent attached to the thiohydroxamate O atom in the title compound, C 13 H 15 NOS 2 , is reflected in a widening of the associated N-O-C angle [116.4 (2) ]. Close contacts along [100] indicate C-HÁ Á ÁS interactions in the crystal structure.

📜 SIMILAR VOLUMES

3-Butyl-4-(3-methyl-3-phenyl­cyclo­but-1
3-Butyl-4-(3-methyl-3-phenyl­cyclo­but-1-yl)-1,3-thia­zole-2(3H)-thione
✍ Kırılmış, Cumhur ;Koca, Murat ;Arıcı, Cengiz ;Heinemann, Frank W. ;Ahmedzade, Mi 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 117 KB

In the title compound, C 18 H 23 NS 2 , the bond lengths and angles are unexceptional. The butyl chain is in a fully extended conformation. The dihedral angle between the thiazole and phenyl rings is 87.21 (2) . The crystal structure is stabilized by one weak intramolecular C-HÁ Á ÁS hydrogen bond.

3-Cyclo­hexyl-4-(3-methyl-3-phenyl­cyclo
3-Cyclo­hexyl-4-(3-methyl-3-phenyl­cyclo­butyl)-1,3-thia­zole-2(3H)-thione
✍ Kırılmış, Cumhur ;Koca, Murat ;Arıcı, Cengiz ;Heinemann, Frank W. ;Ahmedzade, Mi 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 128 KB

The cyclohexyl ring of the title compound, C 20 H 25 NS 2 , has a chair conformation. The dihedral angle between the thiazole and phenyl rings is 89.70 (2) . The crystal structure involves two weak intramolecular C-HÁ Á ÁS hydrogen-bond contacts.

4′-(2,4-Di­chloro­phenyl)-1′-methyl-2,3,
4′-(2,4-Di­chloro­phenyl)-1′-methyl-2,3,2′′,3′′-tetra­hydro-1H-indole-3-spiro-2′-pyrrolidine-3′-spiro-2′′-(1,3-benzimidazo­[2,1-b]­thia­zole)-2,3′′-dione
✍ Li, Xiao-Fang ;Feng, Ya-Qing ;Shi, Da-Xin ;Chen, Hong-Liang 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 170 KB

In the title compound, C 26 H 18 Cl 2 N 4 O 2 S, the two spiro junctions link a planar 2-oxindole ring, a pyrrolidine ring in an envelope conformation and a planar benzo [4,5]imidazo[2,1-b]thiazol-3-one ring. Molecules form dimers connected by NÐHÁ Á ÁN hydrogen bonds.

5-[(2-Hydro­xy­phenyl)­methyl­ene­amino]
5-[(2-Hydro­xy­phenyl)­methyl­ene­amino]-1,3,4-thia­diazo­le-2(3H)-thione
✍ Zhang, Yu-Xia 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 123 KB

The title compound, C 9 H 7 N 3 OS 2 , is essentially planar and features an intramolecular OÐHÁ Á ÁN interaction. Centrosymmetrically related molecules associate via NÐHÁ Á ÁS contacts.