3 1 ,3 2 ,3 3 -TRIMETHYL-AURIN (ORTHO-CRESAURIN) AND 3 1 ,3 2 ,3 3 -TRIMETHYL-N 1 ,N 2 ,N 3 -TRIPHENYL-PARA-ROSANILINE (TRIPHENYL-ROS-ORTHO-TOLUIDINE)
✍ Scribed by Gomberg, M.; Anderson, L. C.
- Book ID
- 126125178
- Publisher
- American Chemical Society
- Year
- 1925
- Tongue
- English
- Weight
- 864 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
In the title compound, C~31~H~21~N~3~O~5~, the indan ring system makes dihedral angles of 53.26 (6) with the nitrobenzene ring, and 66.50 (6) and 58.39 (7)° with the two phenyl rings. The crystal packing is stabilized by weak intermolecular N—H...O and C—H...O hydrogen bonds.
The title compound, C 16 H 21 N 3 O 2 S, is a thiourea derivative with cinnamoyl and 2-morpholinoethyl groups attached at the terminal two N atoms. The groups lie trans and cis, respectively, to the S atom across the thiourea CÐN bonds and the morpholine group adopts a chair conformation. The molecu