(2S,3R,4S)-4-(1,1-Dimethylethoxycarbonylamino)-2,3-epoxy-5-phenylpentanoic Acid Ethyl Ester
✍ Scribed by Weber, H. P. ;Scholz, D. ;Schmidt, H. ;Gstach, H.
- Book ID
- 114511596
- Publisher
- International Union of Crystallography
- Year
- 1995
- Tongue
- English
- Weight
- 327 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0108-2701
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
At 173 K, the ®ve-membered ring of the title compound, C 22 H 26 N 2 O 5 , has an envelope conformation. The amine group is involved in both intramolecular and intermolecular hydrogen bonds, the latter linking the molecules into centrosymmetric dimers. ## Experimental The title compound was prepa
The relative con®guration of the title compound, C 18 H 27 NO 4 , was determined as being R,S,S,S. There are three crystallographically independent molecules in the asymmetric unit, which show only slight conformational differences. Molecules in the crystal structure are connected by hydrogen bonds
Methoxycyclitol 4 was acetalized in a non-classical one-pot idene moiety was realised in two steps via the corresponding ethylidene acetals 8 and 9; the ethylidene function was procedure with chloral/dicyclohexylcarbodiimide forming the 4-epi derivative 6. The stepwise deprotection of removed with a