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(2R,3R,4R)-Meth­yl 2-bromo-3,4-dihydr­oxy-3,4-O-isopropyl­idenetetra­hydro­furan-2-carboxyl­ate

✍ Scribed by Probert, Michael R. ;Watkin, David J. ;Stewart, Alistair J. ;Storer, Richard ;Fleet, George W. J.


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
389 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


The relative configuration of the quaternary C atom in the title bromide, C 9 H 13 BrO 5 , prepared by bromination of the parent ester, has been determined by X-ray crystallographic analysis; the absolute configuration is known from the synthesis.


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✍ Fan, Hong-Tao ;Schürmann, Markus ;Preut, Hans ;Krause, Norbert 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 108 KB

In the title compound, C 14 H 30 O 4 Si, the bond angles around Si are in the range 105.4 (3)-112.1 (4) and the tetrahydrofuran ring adopts a distorted envelope conformation. There is one intramolecular and one intermolecular O-HÁ Á ÁO hydrogen bond in the crystal structure. A spiral of molecules fo