(2R,3R,4R)-Methyl 2-bromo-3,4-dihydroxy-3,4-O-isopropylidenetetrahydrofuran-2-carboxylate
✍ Scribed by Probert, Michael R. ;Watkin, David J. ;Stewart, Alistair J. ;Storer, Richard ;Fleet, George W. J.
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 389 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The relative configuration of the quaternary C atom in the title bromide, C 9 H 13 BrO 5 , prepared by bromination of the parent ester, has been determined by X-ray crystallographic analysis; the absolute configuration is known from the synthesis.
📜 SIMILAR VOLUMES
The title compound, C 13 H 16 O 7 , was extracted from fresh cranberries (Vaccinium macrocarpon). In the crystal structure, molecules are linked into a two-dimensional framework via O-HÁ Á ÁO hydrogen bonds.
In the title compound, C 14 H 30 O 4 Si, the bond angles around Si are in the range 105.4 (3)-112.1 (4) and the tetrahydrofuran ring adopts a distorted envelope conformation. There is one intramolecular and one intermolecular O-HÁ Á ÁO hydrogen bond in the crystal structure. A spiral of molecules fo