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6-(Acetoxy­meth­yl)-5-chloro-2-[(2R,3R,4R,5S)-3,4-diacet­oxy-2,5-bis­(chloro­meth­yl)-2,3,4,5-tetra­hydro­furan-2-yl­oxy]-3,4,5,6-tetra­hydro-2H-pyran-3,4-diyl diacetate toluene solvate

✍ Scribed by Wen, Hui-Liang ;Fang, Zhi-Jie ;Wu, Zi-Sheng ;Xie, Ming-Yong


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
297 KB
Volume
62
Category
Article
ISSN
1600-5368

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2-[(2R,3S,4S,5S)-3,4-Benz­yloxy-2,5-bis(
✍ Wu, Zi-Sheng ;Liu, Chong-Bo ;Wang, Yuan-Xing ;Fang, Zhi-Jie ;Wen, Hui-Liang 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 163 KB

In the sugar molecule of the title compound, C~104~H~94~O~11~·CH~4~O·0.75C~4~H~8~O, the pyranose ring adopts the expected chair conformation. Weak intra- and intermolecular C—H...O hydrogen bonds, in part, control the molecular conformation and stabilize the crystal structure.