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(2S,3R,4R,5R)-2-(tert-Butyldimethylsilyloxymethyl)-2,4,5-trimethyltetrahydrofuran-3,4-diol

✍ Scribed by Fan, Hong-Tao ;Schürmann, Markus ;Preut, Hans ;Krause, Norbert

Publisher: International Union of Crystallography
Year: 2005
Tongue: English
Weight: 108 KB
Volume: 61
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536805016831

No coin nor oath required. For personal study only.

✦ Synopsis

In the title compound, C 14 H 30 O 4 Si, the bond angles around Si are in the range 105.4 (3)-112.1 (4) and the tetrahydrofuran ring adopts a distorted envelope conformation. There is one intramolecular and one intermolecular O-HÁ Á ÁO hydrogen bond in the crystal structure. A spiral of molecules forms around the 4 1 axis (c axis) of the crystal structure via the intermolecular O-HÁ Á ÁO hydrogen bond.

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(2S,3R,4R,5R)-2-(tert-Butyl­dimethyl­silyloxymeth­yl)-2,4,5-trimethyl­tetra­hydro­furan-3,4-diol

✦ Synopsis

(2S,3R,4R,5R)-2-(tert-Butyldimethylsilyloxymethyl)-2,4,5-trimethyltetrahydrofuran-3,4-diol