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(2R,2′S)-2,2′-(Ethane-1,2-diyldiiminio)bis(butane-2,1-diyl) disulfate dihydrate

✍ Scribed by Bai, Guo-Yi ;Zhang, Chen-Fang ;Simpson, Jim ;Chen, Yong ;Peng, Hong-Wei

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 233 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807003480

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✦ Synopsis

The title compound, C~10~H~28~N~2~O~10~S~2~, was synthesized by the reaction of concentrated sulfuric acid with (R,S)-ethambutol. The zwitterionic amino–sulfate system, protonated at both N atoms, lies about a centre of symmetry. The asymmetric unit also contains a solvent water molecule. In the crystal structure, intermolecular O—H...N and N—H...O hydrogen bonds link the molecules into a three-dimensional network.

📜 SIMILAR VOLUMES

(R,S)-2,2′-(Ethane-1,2-diyldiiminio)dibu

(R,S)-2,2′-(Ethane-1,2-diyldiiminio)dibutan-1-ol dinitrate

✍ Bai, Guo-Yi ;Zhang, Chen-Fang ;Simpson, Jim ;Ning, Hui-Sen ;Peng, Hong-Wei 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 176 KB

The asymmetric unit of the title compound, C 10 H 26 N 2 O 2 2+ Á-2NO 3 À , comprises one half of an N-diprotonated (R,S)ethambutol cation, which lies about a centre of symmetry, and a nitrate anion. In the crystal structure, a two-dimensional network is formed via intermolecular O-HÁ Á ÁO and N-HÁ

(S,S)-2,2′-(Ethane-1,2-diyldiiminio)dibu

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✍ Bai, Guo-Yi ;Ning, Hui-Sen ;Zhang, Yue-Cheng ;Zeng, Tao ;Li, Jiang-Sheng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 222 KB

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Bis(ferrocenecarbaldehyde) (1,2-diphenyl

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✍ Zhou, Jing ;Yan, Lin ;Bi, Dong-Qin ;Li, Ming-Xue 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 200 KB

In the title compound, [Fe 2 (C 5 H 5 ) 2 (C 26 H 20 N 4 )], two ferrocene units are bridged by a Schiff base linker with an intramolecular FeÁ Á ÁFe separation of 7.42 (2) A ˚.

(S,S)-1,2-Bis(1-methylbenzimidazol-2-yl

(S,S)-1,2-Bis(1-methylbenzimidazol-2-yl)-1′,2′-bis(methoxy)ethane

✍ Stibrany, Robert T. ;Schugar, Harvey J. ;Potenza, Joseph A. 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 334 KB

3,3′-Diethyl-1,1′-(ethane-1,2-diyl)diben

3,3′-Diethyl-1,1′-(ethane-1,2-diyl)dibenzimidazolium dibromide dihydrate

✍ Wu, Xiu-Mei ;Liu, Qing-Xiang ;Wang, Xiu-Guang ;Song, Hai-Bin ;Zheng, Zhan-Ying 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 586 KB

The title compound, C~20~H~24~N~4~ ^2+^·2Br^−^·2H~2~O, was prepared from benzimidazole by stepwise alkylation with ethyl bromide followed by 1,2-bromoethane. The dication lies about a twofold rotation axis through the centre of the ethanyl group that links the two planar benzimidazolium residues. Th