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(−)-2C-Methyl-d-erythrono-1,4-lactone is formed after application of the terpenoid precursor 1-deoxy-d-xylulose

✍ Scribed by Monika A Fellermeier; Ulrich H Maier; Silvia Sagner; Adelbert Bacher; Meinhart H Zenk

Book ID
117109883
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
74 KB
Volume
437
Category
Article
ISSN
0014-5793

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📜 SIMILAR VOLUMES

Direct formation of 2-C-methyl-d-erythri
Direct formation of 2-C-methyl-d-erythritol 4-phosphate from 1-deoxy-d-xylulose 5-phosphate by 1-deoxy-d-xylulose 5-phosphate reductoisomerase, a new enzyme in the non-mevalonate pathway to isopentenyl diphosphate
✍ Tomohisa Kuzuyama; Shunji Takahashi; Hiroyuki Watanabe; Haruo Seto 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 260 KB

1-Deoxy-D-xyluiose 5-phosphate is biotransformed to 2-C-methyl-D-erythritol 4-phosphate in a single step in the presence of NADPH by a new recombinant enzyme named l-deoxy-D-xylulose 5-phosphate reductoisomerase purified from Escherichia coli.

Elucidation of the 2-C-methyl-d-erythrit
Elucidation of the 2-C-methyl-d-erythritol 4-phosphate pathway for isoprenoid biosynthesis: straightforward syntheses of enantiopure 1-deoxy-d-xylulose from pentose derivatives
✍ Jean-François Hoeffler; Catherine Grosdemange-Billiard; Michel Rohmer 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 65 KB

Optically pure 1-deoxy-D-xylulose, a key metabolite for feeding experiments in the methylerythritol phosphate pathway for isoprenoid biosynthesis, is conveniently synthesised from 1,2-O-isopropylidene-a-D-xylofuranose or from D-arabinose. This renders labelling with hydrogen isotopes possible.