A seven-coordinated tin(IV) complex: dichloro[2,6-diacetylpyridine bis(S-benzyldithiocarbazato-j 5 S,N,N 0 0 0 ,N 0 0 00 0 0 ,S 0 0 0 ]tin(IV) Gerima ´rio F. de Sousa, a \* Jesu ´s Valde ´s Martı ´nez b and Simo ´n Herna ´ndez-Ortega b a
[2,6-Diacetylpyridine bis(4-ethylthiosemicarbazonato)-κ5N,N′,N′′,S′,S′′]dimethyltin(IV) dichloride
✍ Scribed by Swesi, Abdurazag T. ;Farina, Yang ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 140 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 120 K Mean (C-C) = 0.009 A Some non-H atoms missing R factor = 0.066 wR factor = 0.176 Data-to-parameter ratio = 21.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [Sn(CH 3 ) 2 (C 5 H 10 N 3 S)Cl], the 1isopropylidene-4-methyl-3-thiosemicarbazidate ligand has a Z configuration and is chelated to the Sn atom through the S and hydrazinic N atoms in a distorted trigonal-bipyramidal pentacoordination environment. The molecular structure is s