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2,2′-Methylenebis(isoindoline-1,3-dione)

✍ Scribed by Jiang, Zhou ;Wang, Jun-Dong ;Lin, Mei-Jin ;Chen, Nai-Sheng ;Huang, Jin-Ling


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
310 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, C~17~H~10~N~2~O~4~, consists of two phthalimide units connected by a methylene bridge. The N—C—N bond angle is 110.64 (12)°. In the crystal structure, the dihedral angle between the two phthalimide units in one molecule is 88.96 (2)°. The crystal packing is stabilized by the π–π overlap of neighboring phthalimide units, with closest interplanar packing distances of 3.470 (1) and 3.626 (7) Å, and by weak C—H...O interactions.


📜 SIMILAR VOLUMES


2-Ethyl­isoindoline-1,3-dione
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Single-crystal X-ray study T = 294 K Mean (C-C) = 0.003 A R factor = 0.043 wR factor = 0.112 Data-to-parameter ratio = 12.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The title compound, C 18 H 12 N 2 O 4 , crystallizes with one halfmolecule in the asymmetric unit. In each molecule, there is a crystallographic centre of inversion at the mid-point of the central C-C bond.

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In the title compound, C~13~H~14~N~2~O~2~, the pyrrolidine ring adopts an envelope conformation. The crystal structure is stabilized by C—H...O and C—H...N hydrogen bonds.