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2,2-Dichloropropionic Acid Residues in White Asparagus

✍ Scribed by T. E. ARCHER; D. G. CROSBY; A. B. CARLTON


Book ID
108797459
Publisher
Institute of Food Technologists
Year
1967
Tongue
English
Weight
200 KB
Volume
32
Category
Article
ISSN
0022-1147

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Synthesis of 14c-labeled 2,2-dichloropro
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## Abstract A widely used herbicide, 2,2‐dichloropropionic acid (dalapon), was synthesized with ^14^C‐labeling in the C‐1 or C‐2 positions. The carboxyl labeled material was prepared in 55% yield by carbonation of 1,1‐dichloro‐ethyllithium at approximately βˆ’104Β°. Starting with trichloroacetic acid,