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(2,2′-Bipyrid­yl)methano­lbis(trichloro­acetato)copper(II)

✍ Scribed by Ma, Xu-Yan ;Dong, Xin-Dian ;Li, Yan-Ping ;Zhang, Zhi-Gang

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
345 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Cu(C 2 Cl 3 O 2 ) 2 (C 10 H 8 N 2 )(CH 4 O)], the Cu II cation is coordinated by bipyridyl N atoms, two trichloroacetato O atoms and one methanol O atom in a distorted tetragonal pyramidal geometry. In the crystal structure, intermolecular O-HÁ Á ÁO, C-HÁ Á ÁO andinteractions are found.

📜 SIMILAR VOLUMES

Bis­(pyridin-2-yl­methano­lato-κ2N,O)­bi
Bis­(pyridin-2-yl­methano­lato-κ2N,O)­bis­(tri­fluoro­acetato)­nickel(II)
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Single-crystal X-ray study T = 110 K Mean '(C±C) = 0.003 A Ê R factor = 0.036 wR factor = 0.080 Data-to-parameter ratio = 11.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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Reaction of potassium hydridotris(5-methyl-3-phenylpyrazoly)borate with copper(II) acetate in methanol at room temperature gives the title compound, [Cu(C 30 H 28 BN 6 )-(C 2 H 3 O 2 )]. The Cu atom is five-coordinated by three N atoms from pyrazolyl groups and two O atoms from the acetate ligand.

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Tris(2,2′-bipyridyl-κ2N,N′)copper(II) hexa­fluoridophosphate
✍ Wang, Li ;Yang, Xue-Yun ;Huang, Wei 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 311 KB

The title compound, [Cu(C~10~H~8~N~2~)~3~](PF~6~)~2~, is a six-coordinate copper(II) complex with a slightly tetragonally elongated octahedral coordination geometry. There are weak C—H...F, C—H...N and π–π stacking interactions in the structure.