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Bis­(pyridin-2-yl­methano­lato-κ2N,O)­bis­(tri­fluoro­acetato)­nickel(II)

✍ Scribed by Bacsa, John ;Zhao, Hanhua ;Dunbar, Kim R.


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
182 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis


Single-crystal X-ray study T = 110 K Mean '(C±C) = 0.003 A Ê R factor = 0.036 wR factor = 0.080 Data-to-parameter ratio = 11.7

For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.


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The title compound, [Cu(CH~3~CO~2~)~2~(C~9~H~7~N~3~O)~2~(H~2~O)], is a mononuclear complex in which the Cu^II^ atom assumes a square-pyramidal coordination geometry. The Cu atom and the aqua O atom lie on a crystallographic twofold rotation axis. In the crystal structure, there are hydrogen bonds an