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2-(Trimethylsilyloxy)furan as a Dianion Equivalent: A Two-Step Synthesis of Functionalized Spirocyclic Butenolides

✍ Scribed by Maulide, Nuno; Markó, István E.


Book ID
121003804
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
68 KB
Volume
8
Category
Article
ISSN
1523-7060

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✍ Alessandro Palmieri; Serena Gabrielli; Roberto Ballini 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 41 KB 👁 1 views

## Abstract The reaction of ketal‐functionalized nitroalkanes with α‐oxoaldehydes, promoted by Amberlyst A21 and followed by acidic treatment of the mixture with Amberlyst 15, avoids isolation of the nitroaldol intermediates and leads directly to formation of the desired furan derivatives.