2-trimethylsilylethyl glycosides. Anomeric deblocking of mono- and disaccharides.
✍ Scribed by Karl Jansson; Torbjörn Frejd; Jan Kihlberg; Göran Magnusson
- Book ID
- 108381580
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 122 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The role of cross‐correlated relaxation between the anomeric proton chemical shift anisotropy (CSA) and its dipolar relaxation with nearby proton on the longitudinal relaxation in mono‐ and disaccharides at two magnetic field strengths has been investigated and shown to directly report
Highly Stereoselective Synthesis of 2-Deoxy-α-glycosides and α-Disaccharides. -Using S-(2-deoxyglycosyl)phosphorodithioates such as (I) as glycosyl donors allows a highly diastereoselective synthesis of 2-deoxyα-glycosides [cf. (III)] and α-disaccharides such as (V). -(BIELAWSKA,