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Determination of the anomeric configuration in carbohydrates by longitudinal cross-correlated relaxation studies: application to mono- and disaccharides

✍ Scribed by Kumar Pichumani; Xiang Zou; Tilak Chandra; Kenneth L. Brown


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
152 KB
Volume
45
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

The role of cross‐correlated relaxation between the anomeric proton chemical shift anisotropy (CSA) and its dipolar relaxation with nearby proton on the longitudinal relaxation in mono‐ and disaccharides at two magnetic field strengths has been investigated and shown to directly report the identity of their anomeric configuration. Copyright © 2007 John Wiley & Sons, Ltd.