2-Methyl-2-nitropropyl methanesulfonate
✍ Scribed by Zhou, Wei ;Xia, Chun-Nian ;Feng, Wen ;Hu, Wei-Xiao
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 271 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, C~5~H~7~NO~5~S, is an ester of methanesulfonic acid and __N__-hydroxysuccinimide in which the N atom has a flattened pyramidal geometry. The molecular arrangement is stabilized by C—H...O hydrogen bonds, forming double-layer sheets that are linked __via__ short C=O...C=O carbonyl
The title compound, C 14 H 12 N 2 O 4 , exists as an enol-imine tautomer, in which a strong intramolecular O-HÁ Á ÁN hydrogen bond is formed. This study verifies the preference of the enol-imine tautomeric form in the solid state.
In the title compound, C~17~H~12~ClN~3~O~5~, the benzene rings are twisted out of the central –C~ar~–C–C(–CN)–C(=O)–N–plane. The dihedral angles between this plane and the aromatic planes are 31.2 (4) and 4.8 (3)°. The C=C double bond is in an __E__ configuration.
The Sn atom of the title compound, [Sn(C 10 H 13 ) 3 (C 6 H 4 NO 2 )], is four-coordinate and possesses a distorted tetrahedral geometry. ## metal-organic papers Acta Cryst. (2005). E61, m1346-m1347 Tian et al. [Sn(C 10 H 13 ) 3 (C 6 H 4 NO 2 )] m1347