𝔖 Bobbio Scriptorium
✦   LIBER   ✦

2-Methoxybenzaldehyde azine

✍ Scribed by Fu, Zhong-Wu

Book ID
104491040
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
702 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The molecule of the title compound, C 16 H 16 N 2 O 2 , is located on a centre of inversion (at the midpoint of the N-N bond), so that only one half of the molecule is crystallographically independent, and it adopts a syn structure with respect to the methoxy group and the aldehyde H atom. The benzene ring and adjacent N atom are coplanar (r.m.s. deviation of 0.017 A for the non-H atoms). The methoxy group deviates from the benzene plane by 0.167 (4) A ˚for the methyl C atom.

📜 SIMILAR VOLUMES

2-Methoxy­benz­aldehyde thio­semicarbazo
2-Methoxy­benz­aldehyde thio­semicarbazone
✍ Selvanayagam, S. ;Yogavel, M. ;Rajakannan, V. ;Velmurugan, D. ;Shanmuga Sundara 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 285 KB
2-Methoxy­benzaldehyde isonicotinoylhydr
2-Methoxy­benzaldehyde isonicotinoylhydrazone
✍ Yang, Song ;Zhang, Shu-Ping ;Wu, Ying-Ying ;Shao, Si-Chang 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 378 KB
4-Methoxybenzaldehyde 2-methylpropanoylh
4-Methoxybenzaldehyde 2-methylpropanoylhydrazone
✍ Guo, Huan-Mei 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 430 KB

The title compound, C 12 H 18 N 2 O 3 , was prepared by the reaction between p-methoxybenzaldehyde and propionylhydrazine. With the exception of the two methyl groups of the i Pr and the H atoms of the OMe group, the molecule is essentially planar. The crystal structure is stabilized by N-HÁ Á ÁO, O

2′-Chloro­acetophenone azine
2′-Chloro­acetophenone azine
✍ Zhao, Pu-Su ;Guo, Huan-Mei ;Jian, Fang-Fang ;Zheng, Jian ;Xiao, Hai-Lian 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 138 KB

The title compound, C 16 H 14 Cl 2 N 2 , was prepared by the reaction of hydrazine with 2-chloroacetophenone at room temperature. The molecule has C 2 symmetry with the midpoint of the N-N bond lying on the twofold axis.